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No. It is already not taxed as income. You can not deduct it again. Actually it’s better to have it deducted from your IRA distribution (above the line) instead of taking a Schedule A deduction for it.
No. When you make a Qualified Charitable Distribution (QCD) to a charity, you are able to exclude the distribution from your income. Therefore, you cannot also take a charitable contribution deduction for it, since it was not included in your income to begin with.
Here's some information you may find helpful: What is a Qualified Charitable Distribution?
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