Sorry, but no. The license code is specific to the Desktop (CD/Download) platform. If you choose to file using the mobile app, it is totally separate from the CD program that you've already purchased.
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If you bought the CD Desktop program why are you using the Online version or App? The Desktop program has more features than the Online version and can do more than 1 return.
If you don't have a CD drive you can download the program. Otherwise you should return the CD and get a refund then you can pay for the online version.