Schedule A, line 14 reports the total of your gifts to charity, so I think you may be referring to line 4, which is your deductible medical expenses.
If so, you need to keep in mind that you can only deduct the amount of your medical expenses that are more than 7.5% of your adjusted gross income. So if your allowed medical expenses are not more than 7.5% of your income, as is typical, you will not have a deduction for medical expenses appearing on line 4 of schedule A. That may be why your standard deduction is more than your itemized deductions.
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