Changing your W-4 to your correct marital status and selecting the correct number of allowances will result in a more accurate calculation of the amount of tax withheld. After you do that, you will see how much federal tax is withheld.
If you want to verify whether that is enough withholding or not, you can use the TurboTax Taxcaster calculator to estimate what your taxes will be for the year.
You can also use the IRS W-4 calculator: http://apps.irs.gov/app/withholdingcalculator/