How and where can I put in my hours donated at Habitat for Humanity?
Unfortunately, no. See IRS Publication 526, Charitable Contributions, page 7: “you can not deduct the value or your time or your services” http://www.irs.gov/pub/irs-pdf/p526.pdf
See IRS Publication 334, Tax Guide for Small Businesses http://www.irs.gov/pub/irs-pdf/p334.pdf Chapter 8, under Expenses that you can not deduct Charitable Contributions