No, health insurance premiums paid for your Employer Insurance are different than Long Term Care Premiums, which are usually paid directly by you to the insurance company, and are deductible as a Medical Expenses, if you itemize deductions.
Long Term Care Insurance covers custodial care expenses.
Here's more info:
https://longtermcare.acl.gov/costs-how-to-pay/what-is-long-term-care-insurance/
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