The optional Refund Processing Service for paying the TurboTax account fees with the federal tax refund and the RPS fee of $39.99 will not be available until all the forms and schedules included in your tax return are finalized for e-filing. In the meantime you can select the option to pay TurboTax with a credit/debit card.
However, be advised the forms and schedules included with your tax return may not yet be finalized so that you can e-file your tax return.
You should also be able to click on Review on the left-hand menu, and it will show you a list of forms in your return that aren’t available yet. It should also show the date they should become available.
See also this TurboTax support FAQ for IRS forms availability.
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