1st time getting turbo tax card can I withdraw cash from it or only purchases? I am not showing State taxes as transmitted does that mean I have to file by mail?

Yes, you can withdraw cash. More details are in the following link.

https://www.turboprepaidcard.com/help-faq-s#ATMusagePIN

If you have any additional questions or need assistance with your Turbo Prepaid Visa Card, please visit TurboPrepaidCard.com or call us toll-free at (888) 285-4169.

Does your State return show Started or Pending?

showing pending

It's not unusual for state returns to remain in pending status several days after the federal return has already been accepted. This is especially common when e-filing first opens in January or early February.

From TurboTax FAQ:
<a rel="nofollow" target="_blank" href="https://ttlc.intuit.com/questions/1901510-why-is-my-state-e-file-still-pending">https://ttlc.intuit.com/questions/1901510-why-is-my-state-e-file-still-pending</a>

They are thiefs