Simple answer: No, because he's not your dependent.
There is something known as a Medical dependent :
If your close relative cannot
be your dependent because he had more than $4,050 of gross income, but
otherwise would have qualified as your dependent (basically that you & other family members provided more than
half his support), then you can include in your deductible medical expenses any
qualifying medical expenses you paid on his behalf just as if he was
your dependent.
EMT training would not qualify