At 32yrs, in a master's program can I list tuition as job-related expenses on taxes? I received a 1098-T from the university and I don't qualified for AOTC or LLC credit.

No.

Up to tax year 2017, job-related expenses were deductible as an itemized deduction subject to the 2% of AGI floor.

Under the Tax Cuts and Jobs Act, the itemized deductions for job-related expenses subject to the 2% of AGI floor are suspended for expenses incurred after December 31, 2017 through 2025.

The expenses of continuing education in your job is a deduction if you are self employed on your Sch C. 

Regular W-2 employees are not allowed to deduct job expenses, including educational expenses.  The self employed may deduct such expenses if  job related, including  maintaining or improving  job skills.