No, you cannot claim 2020 education expense this year. If you didn't claim in 2020 it then you will need to file an amended tax return (Form 1040-X). Please see How do I amend my 2020 return?
Please verify line 29 on the 2020 Form 1040 if you received the American Opportunity Credit or check Schedule 3 for Education Credit. You can also check if Form 8863, Education Credits was included on your 2020 return.
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