Items include Clothes, Furniture, Cars, Etc. This category covers most things that are not money, stocks or mileage. Since you did not send the rescue money, it would not be considered a monetary donation, it would be considered an item.
When you go through the items section, you should be able to enter a description of the item and that is where you would enter cat food. Regardless of the type of items, it will end up going on line 12 on Schedule A. Cash donations go on line 11 of Schedule A.
It is not advisable to lump it all together as a single donation valued at more than $250, you will need to have written acknowledgement from the rescue stating that you did make the donation.
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