No, you cannot deduct the medical expenses for which your uninsured motorist coverage reimburses you. The only medical expenses you can use are any that you pay yourself out of pocket and for which you are not reimbursed, covered by insurance, etc. And then you can only use the ones that are 7.5% above your adjusted gross income. And, if your itemized deductions including the medical expenses that are deductible, plus any other deductions such as mortgage interest, etc. do not exceed your standard deduction, they have no effect at all on your refund or tax due.
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