You will need to print and mail your return as the IRS will not accept the return electronically without your spouses ITIN/SSN. On the return you can include a note that says she does not have a SSN or ITIN or you can apply for the ITIN using for W7.
If you are filing jointly and want to apply for an ITIN, you will need to print and mail your return along with the W-7 and any other required documents to
IRS
ITIN Operation
P.O. Box 149342
Austin, TX 78714-9342
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