Typically, box 14 is informational and therefore is likely just showing you the breakout of the total local taxes paid (box 19). The box 14 category will be "Other (not classified) since box 19 has the total amount of local taxes paid.
As @JulieS mentions you will need to enter one PA state line for the form W2 that has the local taxes paid (box 19) with a single locality description (box 20).
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