Hi kashleydb,
You will need to keep records and receipts of all expenses. If the company provides the vehicle, I assume that your husband has no expenses associated with it. If there are any expenses that are associated with the vehicle than he should definitely keep an accounting of them. The self-employed income will probably generate a 1099-NEC which will reflect the amount paid for the year. Any expenses incurred such as unloaders, CB radio, small tools, gloves etc should be recorded. My suggestion would be to create a checking account that is solely set aside for the business. That way there is no doubt about the business use. All Estimated payments can be taken from the account with this documentation.
Finally estimate the earnings for the year as best you can so that you have a good idea what the estimated payments should be. Here is a link that will help you to calculate the estimate income.
https://turbotax.intuit.com/tax-tools/calculators/taxcaster/
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