Karen, I missed that you are amending 2020.... As you pointed out, on the 2020 NC return, total deductions are on Line 9 of D-400 and the Bailey settlement portion on Line 21 of the 2020 Schedule S. There is also a Retirement Benefits Worksheet (Retire Ben Wks) where you should see the deduction - Line 4. You should see the federal taxable amount and the NC deduction on Line 4 there.
Since you are amending 2020, you should see the tax changes on your D-400 AM (Amended Schedule).
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