1. Yes, she can file anytime.
2. You should have bank records where you are paying your ex.
3. They will just take her share from your paycheck.
If for some reason you decide to quit paying, then your spouse will surely fill out the paperwork pretty quickly to have it coming directly to her instead of through you. As long as she is happy with your payments, there is no reason to apply for direct payments under the USFSPA.
@HelicopterMekanik
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