No, you can't do anything and are confused. You have two parts - income and tax. You received vested RSU but did not sell them. At the time they vested:
Income
The full market value is in box 1 taxed as part of your ordinary income.
Tax
Taxes are withheld on the market value of the stocks The supplemental rate of 22% refers to the federal withholding tax rate that employers may use to withhold taxes on supplemental wages, which include bonuses and RSUs.
If you sell the RSUs, then you will receive a 1099-B to report profit or loss and the sale follows normal tax laws for stock sales.
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