Distributions from 529 plans must be used to pay qualified expenses in the same calendar as the distribution. If you took a distribution in 2022, it can only be used for payments made in 2022. Payments made in 2021 don't qualify, even if the academic period was 2022. If you had qualified education expenses paid in 2022 that you can "match" that distribution with, it will be a qualified distribution. Otherwise, it's not a qualified distribution.
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