If this is a multi-member LLC, the other member(s) (partners) may have an issue with the payment.
If you have a single-member LLC, perhaps the real question is whether or not you can deduct the payments as a business expense. If that is the case, refer to the link below (scroll down to the bottom).
https://www.thebalancesmb.com/deducting-education-expenses-for-employees-and-owners-398952
