Yes, you can claim your daughter's medical expenses that you paid out-of-pocket, even if she is not your dependent.
This is what the IRS says:
You can include medical expenses you paid for an individual that would have been your dependent except that:
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He or she received gross income of $4,050 or more in 2016,
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He or she filed a joint return for 2016, or
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You, or your spouse if filing jointly, could be claimed as a dependent on someone else's 2016 return.
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