Yes.
Any education expenses paid are treated as being paid by the student (if the student is not a dependent) or the person claiming the student (if a dependent).
If you mean TurboTax Free, no, she would need to upgrade.
If the American Opportunity Tax Credit is still available for her, she could get a refund since that credit is refundable. Any times that credit was used (by you or anyone claiming her) count as part of the four-time limit.
If she is only eligible for the Lifetime Learning Credit, that could lower (or zero-out) her tax liability, but is non-refundable.
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