No, you can not deduct the donation of a timeshare week as a charitable deduction. The IRS has a rule(1) that states, the use of a property, or the permission to use and occupy a property, is not considered a gift of property.
A donor cannot continue to enjoy control over donated funds or property contributed; the gift must be irrevocable to qualify for the charitable deduction.
A contribution of the right to use property is a contribution of less than your entire interest in that property and isn't deductible.
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