If your home is considered your principal place of business, your mileage between your home and your clients and between your clients to your W-2 job. If your first or last stop of the day is between your W-2 job and your home, it is not deductible. In this whole scenario, I am assuming that you are self-employed and are reporting your income and expenses as a sole proprietor on Schedule C.
IRS Publication 463
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