You don't have to fill out any exemptions on MW507. Just enter EXEMPT on line 5 of the form.
Since you are a resident of PA, you don't have to have MD taxes withheld from your paycheck just PA..
PA and MD have a reciprocity agreement--an agreement between two states that
allows residents of one state to request exemption from tax withholding in the
other (reciprocal) state. This can save you the trouble of having to file
multiple state returns in the future. File exemption form MW507
with your employer so that MD taxes won't be taken out in the future (just PA
taxes).
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