After you file

All debit cards, regardless of who issues the card, will have a bank routing and account number for each debit card issued. 

all of this information I am retrieving from the Direct Express website

this is where our communication is getting confused. Direct Express MasterCard is a “PrePaid” card, not a debit card. 
No payments (except returns for purchases made with the card or PayPerks prizes) can be added to the card—it's only for the funds you receive for your federal benefits payments”