The DC government says that this income is taxable on the federal return and in DC:
"What you need to know about paid family leave and taxes:
Benefits you receive under this program are taxable and included in your federal and District gross income. You will receive a Form 1099-G from the District reporting the payments you received during the year.
If you are a non-District resident, please contact the appropriate state tax agency for guidance on taxability of benefits in your state." See this DC webpage.
Note that the second paragraph leaves open the possibility that the benefits might not be taxable in your state of residence.
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