Yes, you can mail a check if you need to, but your federal tax payment would need to be sent to the IRS and your state payment would need to go to your state's taxing authority. You can do direct payments for your federal return at the IRS website. There are other payment option available from this link as well.
And most states allow direct payments at the states' website, which you can find in this chart. TurboTax will print instructions with the mailing address for paper checks if you decide to go that route.
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