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@pk , Thank you for the answer.

We are relocating to the US next week. 

We are both citizens from another country.

 

As far as I know, to become a  US resident, we have to live at least 183 days in the US.  

 

However, until we are not residents, can I choose MFJ status in W-4 form?

 

My wife is going to work after she gets EAD.