EFTPS to pay 2020 taxes?

Can I use the EFTPS system to pay for taxes owed on my 2020 taxes?

 

I filed in February and have a payment plan to pay no later than June 25th. Can I use this system to pay those taxes?

 

Edit to add: I do not know what form to choose on that system to pay back those taxes. 

I also wanted to know what form to choose to pay back estimated quarterly taxes for my food delivery (Uber Estes and Doordash) jobs