It may be that the IRS has not processed your tax return yet, so the debit may show up later in PayPal. The IRS would send you a bill after they processed your tax return if the payment did not get made for some reason. You can pay the tax online or with a check, but it may get debited again if you do that. If that happened, the IRS would probably refund the extra payment, but no right away necessarily.
Your taxes are not due until May 17 this year, so I suggest you wait until then to send a payment if the debit doesn't go through.
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