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A guess for why the "V" is because there are 2 types of vouchers.  The 1040-ES and the 1040-V.  I had the same question initially because I didn't understand the difference between the two. 

But, the 1040-V is for sending in with your current year's tax return when you owe the Feds.  The 1040-ES is for paying the following year's taxes.  I'm not any kind of expert, so check on the above before you believe it.