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He does not qualify to file as Head of Household.  For the purposes of the Head of Household filing status, a qualifying person is a child, parent, or relative who meets certain conditions that enable you to qualify for Head of Household.

Do I qualify for Head of Household?

https://ttlc.intuit.com/replies/3288637

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He maybe able to claim you as a dependent.  See the following

Who can I claim as my dependent?

https://ttlc.intuit.com/replies/5187060