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As I stated in you other question, pre-tax insurance lowers Box 1 and Box 3 and Box 5.  So the W-2 does NOT tell if it is pre-tax or not.  You need to look at your pay-stubs to determine if it is pre-tax or not (and the can sometimes be difficult to tell).  As both Katrina and I said, it is quite unusual for health insurance to NOT be pre-tax.

Box 12, Code DD is for insurance through the employer.  It does not matter if it is pre-tax or not.