Yes. You have two reportable events here. First, the vesting of the options, which is ordinary income reported on your W-2. Second, the sale of the stock, which is reported on your Form 1099-B. The key is to adjust your basis in the stock, if necessary, so that it equals the amount of ordinary income reported on your W-2 for the vesting. The result will be no gain, or often a small loss due to trading fees, on the subsequent sale.
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