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I'll add an example to help clarify my response above but excuse my napkin tax math as I don't have 2025 turbotax with the new brackets and deductions - so pls verify but hopefully this helps illustrate:

 

If you're single and over 65 your standard deduction for 2025 will be 15750+6000 =21,750 

 

Taxable income bracket for 0% LTCG rate is $48350.  Ordinary income "fills up this bucket" first, whatever space is left for your LTCG is taxed at 0% the rest at 15%.  So the bigger the Roth Conversion the more you push your LTCG into the 15% rate

 

If you do a $30k Roth conversion plus $4k RMD your taxable income will be 30000 + 4000 + 36000 - 21750 =48,250.  Your LTCG will be fully 0%.  You will pay tax on $12250 = $1232 (almost all in the 10% bracket).

 

Good deal so far.  But if you do a 100k Roth conversion your taxable income will be 100000 + 4000 + 36000 - 21750 =118,250.  You will now pay 15% rate on the full $36k LTCG for $5400; plus ordinary tax on 82250 is $13009 (15.82%).  Your total tax will be $18409.  The additional 70k in Roth Conversion is triggering additional 18409-1232 =17,177 in tax including the LTCG effect, so this extra conversion is effectively being taxed at 25% (not great).

 

Note this does not take into account any taxable interest or dividends you must surely have on the $20k in Brokerage and the 14k you put into the CD etc.

 

Other conversion amounts in-between 30k and 100k will partially trigger the 15% LTCG rates.

 

If this LTCG is a one-off you are probably better off doing a smaller Roth this year that preserves the 0% LTCG rate but your wealth advisors should advise on that.

 

Not a CPA, hope that helps.