I owed state taxes (for two states!) it was supposed to come out of my account that I have set up. It hasn’t. Where do I look to make sure this was set up correctly?

TurboTax asked if I wanted to use the account I have set up for my federal refund, I said yes, but it hasn’t come out today. It is a lot of money because my company’s payroll company failed to take it out for the whole year. They said I had my state withholding status as exempt which is crazy. I haven’t used exempt since I was in high school. I owe the state thousands. Also it mentioned I have a penalty, but I don’t see where that is. I filed April 6.