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In the dialog for entering the data for a 1099-R, after entering the data amounts there is a series of questions about the payment and the plan.

 

On the screen titled "Was This Distribution From a Qualified Plan" you check one of the two boxes to answer it.  

 

Note that the list of types of plans that are 'non-qualified' it does not include any mention of annuities.  That is probably because not all annuities are 'non-;qualified'.  

 

If your annuity is fixed and you have no way of taking a loan from it, or otherwise cashing it in, etc., I would think it is probably 'non-qualified'.  If you are not sure, you may have to contact the plan.