Yes, if your wife is assigned a SSN, you will be able to file electronically. Just a word of caution however, if you choose to file Married Filing Jointly in the first year and then decide to File Married Filing Separate in later years, "neither spouse can make this choice again in any later tax year, even if married to a different individual – it is a once-in-a-lifetime choice".
Please read the section Ending the Choice in this IRS publication. You are only allowed to make this switch once.
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