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The type of legal separation that allows you to be considered unmarried and file as single is very narrow, and I have never seen a tax court case where someone actually qualified.  See a local attorney if you want to review your personal situation.

 

As a result, your options are generally going to be married filing jointly, married filing separately, or head of household if you meet the qualifications.  You can always file jointly if you are married and your spouse agrees to file jointly.