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I did a mock return and found TurboTax to be calculating properly.

The federal column of Line 5e is showing the lesser of $10,000 or Line 5d. The columns Delaware Spouse and Delaware Taxpayer are being copied from the line above. In my mock return, the two columns do not equal $10,000, as you can see from the screenshot below. Therefore, your columns should not specify $5,000 for one spouse and $5,000 for the other to equal the $10,000. 

Furthermore, on Schedule A PIT-RSA, the $10,000 is being deducted on Line 7, as it should be since that is the maximum amount allowed, unless you are married filing separately.