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you need to find out the Fair Market Value on the day she died in 2019. Whether the 195K is 2/3 of FMV as used for inheritance taxes in PA is unknown

it would seem your older brother owned 1/3 and did not inherit a portion

 

 

 

for you and your sister the tax basis for gain or loss is 1/3 of the FMV on date of death. if 195K was the true FMV of 2/3 of the property than each of you uses 1/2 as their basis 

from the gain your share of selling (certain closing costs) costs would be deducted

 

your older brother, it would be chis cost basis.