Taxes are often calculated using a different method than the tax tables. For example, if you have capital gains, the tax on those is calculated at the capital gain rate for your income level. If you are self-employed, you may have self-employment taxes in addition to income taxes.
You can preview your return before filing to review all of the forms and worksheets that TurboTax has prepared from your entries and to find out how your taxes were calculated. See here for details.
See this help article and this IRS link for more information regarding charitable contributions.
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