I believe what you mean is that you sold some of your restricted stock units (RSU's) when you took possession of them to pay in estimated taxes due on the resulting income. If so, then yes, the tax withheld should be reported on your W-2 form in box 2 automatically. As such, it will appear on your form 1040 on line 25(a) and you will get credit for it on your federal tax return.
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