Sounds like you are right on track using Goodwill values to sell your used items online.
You don't have to submit that info with your tax return, but definitely save documentation for how you determined the amount of your Self-Employment Income (bank deposits, PayPal statements, etc.)
To claim Business Vehicle Expenses, you will enter your vehicle info in that section of of Self Employment Expenses.
You will need to keep track of mileage to/from thrift shops and yard sales to claim 'Business Miles'. You can use a notebook or calendar, or any method that works for you, to keep track of these miles.
Again, you don't need to submit your mileage records with your tax return, but save them with your tax documents.
Click this link for detailed info on Self Employment Expenses.
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