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You will be liable for tax on the profit only.
The first question would be "Are you selling this as an occupation (Schedule C Self-Employed Taxpayer) or was this a one time event similar to a garage sale?"
If this is an occupation, you might have an inventory of books. You would report the full income on Schedule C (as Self-Employed) and then also claim the expenses of the items you sold. You could also claim expenses such as a home office or supplies. Eventually, you would claim the profit as self-employed income and pay income tax as well as Self-Employment tax (FICA). You can be Self-Employed and also hold a W-2 job, in which case you would file a W-2 for the job income and a Schedule C for the Self-Employment.
You would use TurboTax Home and Business Desktop or Self-Employed Online.
If this was more like selling personal items in an online garage sale, you would report the income as capital gain.
You must separate any short-term sales (sales of items you owned for less than one year) from Long-Term (owned one year or more) and also items sold at a gain from those that sold at a loss. As personal items, you must claim the gain, but you can't deduct (subtract) the loss.
The gain (on personal sales) will be reported and taxed as Capital Gain on your return.
Thank you so much for your answer! This helped me determine how to file this portion from Mercari, so I greatly appreciate your input!
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