Unfortunately, this may not be the solution.
You can try mocking up MFS returns for both of you to see if it works any
better but read the text below.
Yes, but there are special rules for allocating when you are
married filing separately that you should review.
Married Filing Separate,
Spousal Abandonment/Suffered Domestic Violence
If you are married but filing separately because your spouse
abandoned you or you suffered domestic violence, it's usually 50% of premiums
and the advanced payment of the premium tax credit. The SLCSP percentage is usually left blank.
Married Filing Separate,
other situations
If you're married but filing
separately and are NOT a victim of domestic abuse or spousal abandonment, then
you do not qualify for the premium tax credit. You must generally
repay all Premium Tax Credit paid in advance as a discount health plan that
covered only the people on your taxes, and half of the PTC paid in advance for
a policy that covered at least one person on your taxes and at least one person
on your spouse's tax family. However, there may be a cap on the amount of
advance payment of the premium tax credit you have to repay.