I run a non-profit and all funds donated goes directly to the program. Since I work for free, is there a way to deduct my hours of work and mileage?

[Opus 17]

You can never take a deduction for the value of your time. When using a car in service of a charity, you can deduct milage at 14 cents per mile.  You must have accurate records of the date, mileage, and purpose of each trip.  You can also deduct out of pocket costs for goods and services you pay for on behalf of the charity.