You can deduct all of your out of
pocket expenses as cash contributions as well as 14 cents per mile for
travelling by auto in the service of your qualified volunteer organization (such as The Red Cross or FEMA).
See IRS Qualified Charity List
To enter volunteer contributions:
Type in charitable contributions. in
the search box, top right of your screen, then click the magnifying glass
Click the jump to charitable
contributions link in the search results.
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Follow the onscreen instructions to enter
To benefit from the above, you must
itemize your deductions.
Unless you
have enough itemized deductions (ie. Medical mortgage interest, property taxes,
charitable giving, ect) to exceed your Standard Deduction, you will not be able
to benefit from this expense.